(3) on charcoal. Fuses to a
bead, which fumes strongly and
incrusts
the charcoal with SbO^{3}, and
sometimes
ZnO, which cannot be volatilized.
Emits
a strong smell of arsenic.
(4) in forceps. —
(5) in borax. The residue
obtained on charcoal thoroughly
roasted
gives a copper reaction, and when the
latter
has been removed by reduction upon
charcoal,
an iron reaction.
(6) in mic. salt. As in the preceding.
(7) with carb. soda. With this
flux and a little borax yields a bead
of
metallic copper; on silver, the alkaline mass
gives
a sulphur reaction.
(8) Special reactions. If the copper
bead obtained by fusing upon
carbonate
of soda be cupelled with assay lead, a
silver
bead will be obtained. Or if dissolved in
nitric
acid and a drop or two of HCl added, a
white
precipitate of AgCl will be formed, which
may
be collected and reduced with carbonate of
soda
upon charcoal.
* * * * *
Mineral. Tennatite
Formula. ([,Cu=][,Fe=])^{4}[,,,As].
Behavior
(1) in glass-bulb. Decrepitates
occasionally and gives a red
sublimate
of [,,,As].
(2) in open tube. Evolves [..S]
and [...As], which condense and
form
a white sublimate.
(3) on charcoal. Fuses to a
magnetic bead giving of arsenical and
sulphurous
fumes.
(4) in forceps. —
(5) in borax. As the preceding.
(6) in mic. salt. As the preceding.
(7) with carb. soda. Yields a copper
bead and metallic iron in the
form
of a dark grey powder. The fused alkali
gives
the sulphur reaction.
(8) Special reactions. —
* * * * *
Mineral. Bournonite
Formula. ([,Pb]^{2}[,Cu=])[,,,Sb].
Behavior
(1) in glass-bulb. Decrepitates
giving off sulfur and, when
strongly
heated, [,,,Sb] and [...Sb].
(2) in open tube. Evolves thick white fumes of [...Sb],[.....Sb] and [.Pb][...Sb]. Also [.S].
(3) on charcoal. Fuses readily
and incrusts the charcoal with
[...Sb]
and [.Pb] leaving a dark colored bead.
(4) in forceps. —


