(1) in glass-bulb. —
(2) in open tube. Evolves SO^{2}
and, when pulverized and gently
heated
for some time is converted into CuO.
(3) on charcoal. Fuses to a
bead, which spirts considerably and
gives
off SO^{2}. When pulverized and gently
roasted,
is converted into CuO.
(4) in forceps. —
(5) in borax. The roasted
mineral gives the copper reaction,
and
sometimes also a slight iron-reaction.
(6) in mic. salt. As in borax.
(7) with carb. soda. In the reducing
flame is decomposed, forming NaS
and
metallic copper. If the former be cut out
and
laid upon silver, it gives the sulfur
reaction.
(8) Special reactions. —
* * * * *
Mineral. Copper pyrites
Formula. [,Cu=][,,,Fe=].
Behavior
(1) in glass-bulb. Decrepitates,
sometimes gives a sublimate of
sulphur
and becomes bronze colored on the
surface.
(2) in open tube. Evolves SO^{2}
and is finally converted into a
dark
red mixture of Fe^{2}O^{3} and CuO.
(3) on charcoal. Fuses readily
with much ebullition and is
magnetic
on cooling.
(4) in forceps. —
(5) in borax. As the preceding;
but when the copper has been
removed
by reducing on charcoal, the bead shows
a
strong iron color.
(6) in mic. salt. As the preceding,
but the color in the oxidizing
flame
is green, owing to the presence of iron.
(7) with carb. soda. Yields a bead
of metallic copper and some
magnetic
oxide of iron which remains on the
charcoal.
The fused gives a sulphur reaction on
silver.
(8) Special reactions. —
* * * * *
Mineral. Fahlerz
Formula. ([,Cu=][,Ag][,Fe][,Zn])^{4} ([,,,Sb][,,,As]).
Behavior
(1) in glass-bulb. Sometimes
decrepitates, fuses, and when very
strongly
heated, gives a red sublimate of
[,,,Sb]
with [...Sb], also sometimes a black
sublimate
of [,Hg] and occasionally [,,,As].
(2) in open tube. Fuses and
gives off thick fumes of SbO^{3} and
SO^{2},
also generally AsO^{3}, leaving a black
infusible
residue. If Hg be present, it is
sublimed
and condenses in the tube in small
drops.


