The Chemistry of Hat Manufacturing eBook

This eBook from the Gutenberg Project consists of approximately 158 pages of information about The Chemistry of Hat Manufacturing.

The Chemistry of Hat Manufacturing eBook

This eBook from the Gutenberg Project consists of approximately 158 pages of information about The Chemistry of Hat Manufacturing.
calcium chloride (CaCl_{2}); and aluminium and iron, triacid salts, for example, aluminium sulphate [Al_{2}(SO_{4})_{3}] and iron (ferric) sulphate [Fe_{2}(SO_{4})_{3}].  Now in these triacid salts we can remove some of the acid groups and substitute the elements of water, OH, or hydroxyl, as it is called, for them.  Such salts, then, only partly saturated with acid, are termed basic salts.  Thus we have Al_{2}(OH)_{2}(SO_{4})_{2}, Al_{2}(OH)_{4}SO_{4}, as well as Al_{2}(SO_{4})_{3}, and we can get these basic salts by treating the normal sulphate [Al_{2}(SO_{4})_{3}] with sufficient caustic soda to remove the necessary quantities of sulphuric acid.  Now it is a curious thing that of these aluminium sulphates the fully saturated one, Al_{2}(SO_{4})_{3}, is the most stable, for even on long boiling of its solution in water it suffers no change, but the more basic is the sulphate the less stable it becomes, and so the more easily it decomposes on heating or boiling its solution, giving a deposit or precipitate of a still more basic sulphate, or of hydrated alumina itself, Al_{2}(OH)_{6}, until we arrive at the salt Al_{2}(SO_{4})_{2}(OH)_{2}, which is quite unstable on boiling; Al_{2}(SO_{4})(OH)_{4} would be more unstable still.  This behaviour may be easily shown experimentally.  We will dissolve some “cake alum” or normal sulphate of alumina, Al_{2}(SO_{4})_{3}, in water, and boil some of the solution.  No deposit or precipitate is produced; the salt is stable.  To another portion of the solution we will add some caustic soda, NaOH, in order to rob the normal sulphate of alumina of some of its sulphuric acid.  This makes the sulphate of alumina basic, and the more basic, the more caustic soda is added, the sodium (Na) of the caustic soda combining with the SO_{4} of the sulphate of alumina to form sulphate of soda (Na_{2}SO_{4}), whilst the hydroxyl (OH) of the caustic soda takes the position previously occupied by the SO_{4}.  But this increase of basicity also means decrease of stability, for on boiling the solution, which now contains a basic sulphate of alumina, a precipitate is formed, a result which also follows if more caustic soda is added, production of still more basic salts or of hydrated alumina, Al_{2}(OH)_{6}, taking place in either case.

Mordanting or Fixing Acid (Phenolic) Colours.—­But what has all this to do with mordanting? is possibly now the inquiry.  So much as this, that only such unstable salts as I have just described, which decompose and yield precipitates by the action on them of alkalis, heat, the textile fibres themselves, or other agencies, are suitable to act as true mordants.  Hence, generally, the sources or root substances of the best and most efficient mordants are the metals of high specific appetite or valency.  I think we have now got a clue to the principle of mordants and also to the importance of a sound chemical knowledge in dealing most effectively with them, and I may tell you that the man who did most to elucidate the theory

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The Chemistry of Hat Manufacturing from Project Gutenberg. Public domain.