Creative Chemistry eBook

This eBook from the Gutenberg Project consists of approximately 310 pages of information about Creative Chemistry.

Creative Chemistry eBook

This eBook from the Gutenberg Project consists of approximately 310 pages of information about Creative Chemistry.

[Illustration:  Courtesy of the Carborundum Company, Niagara Falls

MAKING ALOXITE IN THE ELECTRIC FURNACES BY FUSING COKE AND BAUXITE

In the background are the circular furnaces.  In the foreground are the fused masses of the product]

[Illustration:  Courtesy of the Carborundum Co., Niagara Falls

A BLOCK OF CARBORUNDUM CRYSTALS]

[Illustration:  Courtesy of the Carborundum Co., Niagara Falls

MAKING CARBORUNDUM IN THE ELECTRIC FURNACE

At the end may be seen the attachments for the wires carrying the electric current and on the side the flames from the burning carbon.]

The temperatures attainable with various fuels in the compound blowpipe are said to be: 

Acetylene with oxygen        7878 deg.  F.
Hydrogen with oxygen         6785 deg.  F.
Coal gas with oxygen         6575 deg.  F.
Gasoline with oxygen         5788 deg.  F.

If we compare the formula of acetylene, C_{2}H_{2} with that of ethylene, C_{2}H_{4}, or with ethane, C_{2}H_{6}, we see that acetylene could take on two or four more atoms.  It is evidently what the chemists call an “unsaturated” compound, one that has not reached its limit of hydrogenation.  It is therefore a very active and energetic compound, ready to pick up on the slightest instigation hydrogen or oxygen or chlorine or any other elements that happen to be handy.  This is why it is so useful as a starting point for synthetic chemistry.

To build up from this simple substance, acetylene, the higher compounds of carbon and oxygen it is necessary to call in the aid of that mysterious agency, the catalyst.  Acetylene is not always acted upon by water, as we know, for we see it bubbling up through the water when prepared from the carbide.  But if to the water be added a little acid and a mercury salt, the acetylene gas will unite with the water forming a new compound, acetaldehyde.  We can show the change most simply in this fashion: 

  C_{2}H_{2} + H_{2}O —­> C_{2}H_{4}O

  acetylene added to water forms acetaldehyde

Acetaldehyde is not of much importance in itself, but is useful as a transition.  If its vapor mixed with hydrogen is passed over finely divided nickel, serving as a catalyst, the two unite and we have alcohol, according to this reaction: 

  C_{2}H_{4}O + H_{2} —­> C_{2}H_{6}O

  acetaldehyde added to hydrogen forms alcohol

Alcohol we are all familiar with—­some of us too familiar, but the prohibition laws will correct that.  The point to be noted is that the alcohol we have made from such unpromising materials as limestone and coal is exactly the same alcohol as is obtained by the fermentation of fruits and grains by the yeast plant as in wine and beer.  It is not a substitute or imitation.  It is not the wood spirits (methyl alcohol, CH_{4}O), produced by the destructive distillation of wood, equally serviceable as a solvent or fuel, but undrinkable and poisonous.

Copyrights
Project Gutenberg
Creative Chemistry from Project Gutenberg. Public domain.