Scientific American Supplement, No. 711, August 17, 1889 eBook

This eBook from the Gutenberg Project consists of approximately 137 pages of information about Scientific American Supplement, No. 711, August 17, 1889.

Scientific American Supplement, No. 711, August 17, 1889 eBook

This eBook from the Gutenberg Project consists of approximately 137 pages of information about Scientific American Supplement, No. 711, August 17, 1889.

By the action of a small quantity of sulphuric acid, among other products terebene is formed.  It has the same boiling point and sp. gr. as terebenthene, but is without action on polarized light.  Austraterebenthene forms similar if not identical bodies.

Polymers.  One part of boron fluoride BF3 instantly converts 160 parts of terebenthene into polymers boiling above 300 deg.  C., and optically inactive.  H2 SO4 does the same on heating and forms diterebene C20 H32.

Terchloride of antimony does the same, and also produces tetraterebene C40H64, a solid brittle compound formed by the union of four molecules of C10 H16.  It does not boil below 350 deg.  C. and decomposes on heating.

Compound with H2O.  Terpin C10 H18 2HO is formed when 1 volume of spirits of turpentine is mixed with 6 of nitric acid and 1 of alcohol, and exposed to air for some weeks.  Crystals are formed which are pressed, decolorized by animal charcoal, and recrystallized from boiling water.

Compounds with HCl.  When a slow current of HCl is passed through cooled spirits of turpentine, two isomeric compounds are formed, one solid, and one liquid.  The lower the temperature is kept, the more of the solid body is produced.  To obtain the solid body pure it is pressed and recrystallized from ether or alcohol.  It is volatile and has the odor of camphor.  It is called artificial camphor, and has the composition C10 H16 HCl.  There is also a compound with 2HCl.

Oxidation products.  By passing air into spirits of turpentine oxygen is absorbed.  It was thought at one time that ozone was produced, but Kingzett’s view is that camphoric peroxide is formed C10 H14 O4, and that in presence of water it decomposes into camphoric acid and H2 O2.  This liquid constitutes the disinfectant known as “sanitas,” which possesses the advantages of a pleasant smell and non-poisonous properties.  C10 H18 O2 may be obtained by exposing spirits of turpentine in a flask full of oxygen with a little water.

Camphor C16 H16 O has been made in small quantity by oxidizing spirits of turpentine.  Terebenthene belongs to the benzene or aromatic series, which can be shown from its connection with cymene.  Cymene is methylpropyl-benzene, and can be made from terpenes by removing two atoms of H. It has not yet been converted again into terpene, but the connection is sufficiently proved.  The presence of CH3 in terpenes is shown by their yielding chloroform when distilled with bleaching powder and water.  The resin is imperfectly known.  It was supposed to consist of picric and sylvic acids.  It is also stated to contain abietic anhydride C44 H62 O4, but it is difficult to understand how a compound containing C44 can be produced from C10 H16.  The most probable view is that it is the anhydride of sylvic acid, which is probably C20 H30 O2.

The dark colored resin which is obtained when the turpentine is distilled without water can be converted into a transparent slightly yellow body by distillation with superheated steam.  A small portion is decomposed, but the greater part distills unchanged.  It is used in making soap which will lather with sea water.

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Scientific American Supplement, No. 711, August 17, 1889 from Project Gutenberg. Public domain.