of the colorific and coloring principles, so far
as they are at present known, showing their chemical
formulae and the authority therefor, and various
relative information. “It is highly probable
that when the chemistry of the lichens has been
more fully studied, and the whole subject of their
color-educts and products better understood, we
shall begin to reduce the present confused mass of
complex substances, and find the same principles
more extensively diffused through different lichen
species.” Dr. L. entered somewhat minutely
on the chemical reactions of the better known colorific
and coloring principles, and their derivatives,
so far at least as these throw any light on the
production and transmutation of the red or purple
colors extracted from what may be termed par
excellence, the dye-lichens. After
a few remarks on the chemical constitution of orchil
and litmus, as given by Kane, Gelis, Pereira, and others,
he discussed the subject of decolorisation of
weak infusions of orchil and litmus by exclusion
of atmospheric air, and by various deoxidising
agents, and the different theories as to the causation
of this phenomenon. “I have repeatedly
had occasion to notice that, when weak infusions
of these substances are excluded for some time from
atmospheric air, in a bottle, with a tightly fitting
cork, they gradually lose color, but rapidly regain
it on re-exposure. It is curious that both
orchil and litmus are what are called transient or
false colors, i.e., they slowly lose their
bloom and tint by long exposure to the atmosphere;
the coloring matter, therefore, appears to be
decolorised both by exposure to, and exclusion from
the air, phenomena apparently of very opposite
characters. The cause of the latter phenomenon
has never, so far as I am aware, been quite satisfactorily
explained; but it has been variously supposed to be
due:—
1. To the mere negation of oxygen.
2. To the development,
in the liquids, of various substances,
capable of exerting a decolorising
influence on the coloring matter.
3. To deoxidation of the coloring matter by substances, which have a great tendency to become oxidised or peroxised; e.g. hydrogen, in the case of decolorisation by sulphuretted hydrogen, nascent hydrogen, and the protoxides of iron and tin, &c.
4. To the fixation of an additional amount of hydrogen in a new colorless body, formed by the union of the sulphuretted hydrogen or other substances with the coloring matter of the liquid. This view is chiefly supported by Kane, who says, “that precisely as the coloring matters combine with water, to form different shades of red-colored bodies—with ammonia to produce a series of bodies, which are blue and purple—so they combined with sulphuretted hydrogen to form colorless compounds in solution, which, if solid, very probably would be white.” He supposes, in a word, that for every colored substance existing


