Scientific American Supplement, No. 829, November 21, 1891 eBook

This eBook from the Gutenberg Project consists of approximately 124 pages of information about Scientific American Supplement, No. 829, November 21, 1891.

Scientific American Supplement, No. 829, November 21, 1891 eBook

This eBook from the Gutenberg Project consists of approximately 124 pages of information about Scientific American Supplement, No. 829, November 21, 1891.
of silicon and of sulphur; and in cases where either ores containing variable percentages of phosphorus, or puddle slags, are treated, the varying proportion of phosphorus has also to be considered.  This disadvantage of the irregular composition of the individual blast furnace charges is obviated in a simple and effective manner by W.R.  Jones’s mixing process.  In this as much pig iron from the various blast furnaces of a works as is sufficient for a large number of Bessemer charges, say from seven to twelve charges, or, in other words, from 70 to 120 tons of pig iron, is placed in a mixing vessel.  Only a portion of pig iron placed in the mixer is taken for further treatment for steel, while new supplies of pig iron are brought from the blast furnace.  In this way homogeneity sufficient for practical purposes is obtained.

In the treatment of phosphoric pig iron, which is employed in the production of basic steel, it is, however, not sufficient merely to conduct the molten pig iron in large quantities to the converter in a mixed condition, but the problem here is to render the proportion of sulphur also independent of the blast furnace process to such an extent that the proportion of sulphur in the finished steel is so low that the quality of the steel is in no way influenced by it.  The question of desulphurization has, especially of late years, become of the utmost importance, at any rate for the iron industry of the Continent.  By the great strike of 1889, the German colliers have succeeded in greatly improving their wages; and with this increase in wages not only is there a distinct diminution in the amount of coal wrought, but, unfortunately, the coal produced since then is raised in a much less pure condition than was formerly the case.  Consequently the proportion of sulphur in the coke has considerably increased.  Whereas formerly this proportion did not exceed one per cent., it has now in many cases risen to 18 per cent.; so that an unpleasant ratio exists between the wages of the workmen and the amount of sulphur in the coal raised.  It is therefore not remarkable that, even when ores fairly free from sulphur are treated, it easily happens that a sulphureted pig iron is obtained.

In order to effect satisfactory desulphurization, attention has been bestowed on the fact that iron sulphide is converted by manganese into manganese sulphide and iron.  If sulphureted pig iron, poor in manganese, is added in a fluid condition to manganiferous molten pig iron, poor in sulphur, the metal is desulphurized, and a manganese sulphide slag is formed.  It may be urged that it does not seem necessary to effect the desulphurization by means of the reaction of the manganese and iron sulphide outside of the blast furnace, as it is possible, by suitably directing the blast furnace, by the employment of manganiferous ores or highly basic slag, so to desulphurize the iron in the blast furnace itself that it would be unnecessary further to lower the percentage of sulphur.  Every

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Scientific American Supplement, No. 829, November 21, 1891 from Project Gutenberg. Public domain.