Experimental Researches in Electricity, Volume 1 eBook

This eBook from the Gutenberg Project consists of approximately 775 pages of information about Experimental Researches in Electricity, Volume 1.

Experimental Researches in Electricity, Volume 1 eBook

This eBook from the Gutenberg Project consists of approximately 775 pages of information about Experimental Researches in Electricity, Volume 1.

567.  It was found by various experiments, that this effect was not due to the escape or solution of the gas, nor to recombination of the oxygen or hydrogen in consequence of any peculiar condition they might be supposed to possess under the circumstances; but to be occasioned by the action of one or both of the poles within the tube upon the gas around them.  On disuniting the poles from the pile after they had acted upon dilute sulphuric acid, and introducing them into separate tubes containing mixed oxygen and hydrogen, it was found that the positive pole effected the union of the gases, but the negative pole apparently not (588.).  It was ascertained also that no action of a sensible kind took place between the positive pole with oxygen or hydrogen alone.

568.  These experiments reduced the phenomena to the consequence of a power possessed by the platina, after it had been the positive pole of a voltaic pile, of causing the combination of oxygen and hydrogen at common, or even at low, temperatures.  This effect is, as far as I am aware, altogether new, and was immediately followed out to ascertain whether it was really of an electric nature, and how far it would interfere with the determination of the quantities evolved in the cases of electro-chemical decomposition required in the fourteenth section of these Researches.

569.  Several platina plates were prepared (fig. 57.).  They were nearly half an inch wide, and two inches and a half long:  some were 1/200dth of an inch, others not more than 1/600dth, whilst some were as much as 1/70th of an inch in thickness.  Each had a piece of platina wire, about seven inches long, soldered to it by pure gold.  Then a number of glass tubes were prepared:  they were about nine or ten inches in length, 5/8ths of an inch in internal diameter, were sealed hermetically at one extremity, and were graduated.  Into these tubes was put a mixture of two volumes of hydrogen and one of oxygen, at the water pneumatic trough, and when one of the plates described had been connected with the positive or negative pole of the voltaic battery for a given time, or had been otherwise prepared, it was introduced through the water into the gas within the tube; the whole set aside in a test-glass (fig. 58.), and left for a longer or shorter period, that the action might be observed.

570.  The following result may be given as an illustration of the phenomenon to be investigated.  Diluted sulphuric acid, of the specific gravity 1.336, was put into a glass jar, in which was placed also a large platina plate, connected with the negative end of a voltaic battery of forty pairs of four-inch plates, with double coppers, and moderately charged.  One of the plates above described (569.) was then connected with the positive extremity, and immersed in the same jar of acid for five minutes, after which it was separated from the battery, washed in distilled water, and introduced through the water of the pneumatic

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Experimental Researches in Electricity, Volume 1 from Project Gutenberg. Public domain.