Scientific American Supplement, No. 470, January 3, 1885 eBook

This eBook from the Gutenberg Project consists of approximately 124 pages of information about Scientific American Supplement, No. 470, January 3, 1885.

Scientific American Supplement, No. 470, January 3, 1885 eBook

This eBook from the Gutenberg Project consists of approximately 124 pages of information about Scientific American Supplement, No. 470, January 3, 1885.
is the same, and the separation of the nearer components impracticable.  The object of analysis consisted in estimating the accompanying impurities of fat, as, resin, albuminoids, and pigments.  The nature of these substances depends on the mode of extraction and preservation of the fat, and are subject in the course of time to alteration.  The only reaction based upon the chemical constitution of fat is produced by treatment of oleic or linoleic acid with nitrous acid, which therefore is of some value in the examination of drying oils.  Of general application are the methods which correspond to the chemical constitution of fats, and thus determine the relative quantity of the components; advantage can then be derived from qualitative reactions, inasmuch as they further affirm the result of the quantitative test, or dispel any doubt with regard to the correctness of the result.  The principal methods which comply with these demands have been carefully studied by Hueble for the purpose of discovering a process of general application; methods founded on the determination of density, freezing, and melting point were compared with those dependent on the solubility of fatty substances in glacial acetic acid or a mixture of alcohol and acetic acid; also the method of Hehner for testing of butter, the determination of glycerine and oleic acid, and at length the process of saponification.  Nearly all fats contain members belonging to one of the three series of fatty acids, e.g., acids of the type of acetic acid (stearic and palmitic acids); such as are derivatives of acrylic acid (oleic and erucic acids); and such as are homologues of tetrolic acid (linoleic acid).  It is likely that the relative quantity of each of these acids is variable, with regard to the same fat, within definite limits, and changes with the nature of the fatty substance.  The groups of fatty acids are distinguished by a characteristic deportment toward halogens; while members of the first series are indifferent to haloids, those of the second and third class combine readily, without suffering substitution, with two respectively four atoms of a haloid.  In view of this behavior the first series is termed saturated, the second and third that of unsaturated acids.  Addition of halogen to one of the unsaturated acids yields on subsequent examination an invariable quantity of the former, representing two or four atoms, according to one or the other of unsaturated groups; and as the molecular weights of fatty acids are unequal, the percentage quantity of halogen will be found varying with regard to members belonging to the same series.  The amount of iodine absorbed by some of the fatty acids is illustrated by the following items: 

Copyrights
Project Gutenberg
Scientific American Supplement, No. 470, January 3, 1885 from Project Gutenberg. Public domain.