An Introductory Course of Quantitative Chemical Analysis eBook

This eBook from the Gutenberg Project consists of approximately 220 pages of information about An Introductory Course of Quantitative Chemical Analysis.

An Introductory Course of Quantitative Chemical Analysis eBook

This eBook from the Gutenberg Project consists of approximately 220 pages of information about An Introductory Course of Quantitative Chemical Analysis.

                                  Salts
============================================================
=============
                                             |
               type of salt | percentage dissociation in
                                             | 0.1 Equivalent solution
_____________________________________________|______________
_____________
                                             |
R^{+}R^{-} | 86
                                             |
R^{++}(R^{-})_{2} | 72
                                             |
(R^{+})_{2}R^{—­} | 72
                                             |
R^{++}R^{—­} | 45
                                             |
============================================================
=============

The percentage dissociation is determined by studying the electrical conductivity of the solutions and by other physico-chemical methods, and the following general statements summarize the results: 

!Salts!, as a class, are largely dissociated in aqueous solution.

!Acids! yield H^{+} ions in water solution, and the comparative !strength!, that is, the activity, of acids is proportional to the concentration of the H^{+} ions and is measured by the percentage dissociation in solutions of equivalent concentration.  The common mineral acids are largely dissociated and therefore give a relatively high concentration of H^{+} ions, and are commonly known as “strong acids.”  The organic acids, on the other hand, belong generally to the group of “weak acids.”

!Bases! yield Oh^{-} ions in water solution, and the comparative strength of the bases is measured by their relative dissociation in solutions of equivalent concentration.  Ammonium hydroxide is a weak base, as shown in the table above, while the hydroxides of sodium and potassium exhibit strongly basic properties.

Ionic reactions are all, to a greater or less degree, !reversible reactions!.  A typical example of an easily reversible reaction is that representing the changes in ionization which an electrolyte such as acetic acid undergoes on dilution or concentration of its solutions, !i.e.!, HC_{2}H_{3}O_{2} <—­> H^{+} + C_{2}H_{3}O_{2}^{-}.  As was stated above, the ionization increases with dilution, the reaction then proceeding from left to right, while concentration of the solution occasions a partial reassociation of the ions, and the reaction proceeds from right to left.  To understand the principle underlying these changes it is necessary to consider first the conditions which prevail when a solution of acetic acid, which has been stirred until it is of uniform concentration throughout, has come to a constant temperature. 

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An Introductory Course of Quantitative Chemical Analysis from Project Gutenberg. Public domain.