This name can refer to several members of the Russian Imperial Family:
- Empress Maria Alexandrovna (1824-1880), born Princess Marie of Hesse and by Rhine, daughter of Grand Duke Ludwig II of Hesse-Darmstadt, and consort of Tsar Alexander II of Russia, and her daughter
- Grand Duchess Maria Alexandrovna (1853 – 1920), daughter of Empress Maria Alexandrovna and Emperor Alexander II, married Prince Alfred, second son of Queen Victoria
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