Half-Life
The half-life (or half-value period) of a substance is the time required for that substance to reduce to a size half of its initial value.
The half-life is most commonly encountered when talking about radioactive decay. Radioactive elements have different isotopes that decay at different rates. As a result the half-life has to be given in terms of the particular isotope under discussion. Some isotopes have very short half-lives, for example oxygen-14 has a half-life of only 71 seconds, some are even shorter with values measured in millionths of a second not being uncommon. Other elements' isotopes can have a much longer half-life, thallium-232 has a half-life of 1.4 x 10 10 years and carbon-14 has a half-life of 5,730 years. This latter figure is used as the basis of radiocarbon dating of once-living organisms. While living, an organism takes in an amount of carbon-14 at a relatively constant rate. Once the organism dies no more carbon-14 is taken in and the amount of carbon-14 present overall starts to decrease, decreasing by half every 5,730 years. By measuring the ratio of carbon-12 to carbon-14 an estimate of the date when carbon-14 stopped being assimilated can be calculated. This figure can also be obtained by comparing the levels of radioactivity of the test material to that of a piece of identical material that is fresh. Other radioactive elements can be used to date older materials such as rocks.
Strontium-90 has a half-life of 29 years. If starting with a 2.2 lb (1 kg) mass of strontium-90, then after 29 years there will only be 1.11 lb (0.5 kg) of strontium-90 remaining. After a further 29 years there will only be 0.55 lb (0.25 kg). Strontium-90 decays to give yttrium-90 and one free electron. It can be seen from this example that the half life is independent of the mass of material present.
The half-life (t1/2)of a material can be calculated by dividing 0.693 by the decay constant (which is different for different radionucleotides). The decay constant can be calculated by dividing the number of observed disintegrations per unit time by the number of radioactive nuclei in the sample. The decay constant is usually given the symbol k or .
When studying chemical reactions the presence of a half-life can also be seen. The half-life in this context is the time taken for a substance to change its concentration to half of its initial value, it is an indication of the rate of the reaction. As with radioactive decay this half life is independent of the concentration. Reactions that proceed very rapidly have a short half-life and slow reactions have a long half-life. The half-life in a chemical reaction must have all participants named otherwise the figure is meaningless.
The half-life of a material is a measure of how reactive it is either in terms of radioactive decay or in participation in a named reaction.
This is the complete article, containing 478 words
(approx. 2 pages at 300 words per page).
