Familiar Letters on Chemistry eBook

This eBook from the Gutenberg Project consists of approximately 119 pages of information about Familiar Letters on Chemistry.

Another important application of sulphuric acid may be adduced; namely, to the refining of silver and the separation of gold, which is always present in some proportion in native silver.  Silver, as it is usually obtained from mines in Europe, contains in 16 ounces, 6 to 8 ounces of copper.  When used by the silversmith, or in coining, 16 ounces must contain in Germany 13 ounces of silver, in England about 14 1/2.  But this alloy is always made artificially by mixing pure silver with the due proportion of the copper; and for this purpose the silver must be obtained pure by the refiner.  This he formerly effected by amalgamation, or by roasting it with lead; and the cost of this process was about 2l. for every hundred-weight of silver.  In the silver so prepared, about 1/1200 to 1/2000th part of gold remained; to effect the separation of this by nitrio-hydrochloric acid was more expensive than the value of the gold; it was therefore left in utensils, or circulated in coin, valueless.  The copper, too, of the native silver was no use whatever.  But the 1/1000th part of gold, being about one and a half per cent. of the value of the silver, now covers the cost of refining, and affords an adequate profit to the refiner; so that he effects the separation of the copper, and returns to his employer the whole amount of the pure silver, as well as the copper, without demanding any payment:  he is amply remunerated by that minute portion of gold.  The new process of refining is a most beautiful chemical operation:  the granulated metal is boiled in concentrated sulphuric acid, which dissolves both the silver and the copper, leaving the gold nearly pure, in the form of a black powder.  The solution is then placed in a leaden vessel containing metallic copper; this is gradually dissolved, and the silver precipitated in a pure metallic state.  The sulphate of copper thus formed is also a valuable product, being employed in the manufacture of green and blue pigments.

Other immediate results of the economical production of sulphuric acid, are the general employment of phosphorus matches, and of stearine candles, that beautiful substitute for tallow and wax.  Twenty-five years ago, the present prices and extensive applications of sulphuric and muriatic acids, of soda, phosphorus, &c., would have been considered utterly impossible.  Who is able to foresee what new and unthought-of chemical productions, ministering to the service and comforts of mankind, the next twenty-five years may produce?

After these remarks you will perceive that it is no exaggeration to say, we may fairly judge of the commercial prosperity of a country from the amount of sulphuric acid it consumes.  Reflecting upon the important influence which the price of sulphur exercises upon the cost of production of bleached and printed cotton stuffs, soap, glass, &c., and remembering that Great Britain supplies America, Spain, Portugal, and the East, with these, exchanging them for raw cotton,

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