Scientific American Supplement No. 819, September 12, 1891 eBook

This eBook from the Gutenberg Project consists of approximately 130 pages of information about Scientific American Supplement No. 819, September 12, 1891.

Scientific American Supplement No. 819, September 12, 1891 eBook

This eBook from the Gutenberg Project consists of approximately 130 pages of information about Scientific American Supplement No. 819, September 12, 1891.

In the majority of refrigerating and ice machines ammonia gas is the substance used for producing the refrigeration, although there are other machines in which other material is employed, one of these being anhydrous sulphurous acid, which is also a gas.  Ammonia of itself is a colorless gas, but little more than one half as heavy as air.  In its composition ammonia consists of two gases, nitrogen and hydrogen, in the proportion by weight of one part nitrogen and three parts hydrogen.  The gas hydrogen is one of the constituents of water and is highly inflammable in the presence of air or oxygen, while the other component of ammonia, nitrogen, forms the bulk or about four-fifths of the atmosphere.  Nitrogen by itself is an inert gas, colorless and uninflammable.  Ammonia, although composed of more than three-fourths its weight of hydrogen, is not inflammable in air, on account of its combination with the nitrogen.  This combination, it will be understood, is not a simple mixture, but the two gases are chemically combined, forming a new substance which has characteristics and properties entirely different from either of the gases entering into its composition when taken alone or when simply mixed together without chemical combustion.  Ammonia cannot be produced by the direct combination of these elements, but it has been found that it is sometimes made or produced in a very extraordinary manner, which goes to show that there is yet considerable to be learned in regard to the chemistry of ammonia.  Animal or vegetable substances when putrefying or suffering destructive distillation almost invariably give rise to an abundant production of this substance.

The common method for the manufacture of ammonia is to produce it from the salt known as sal-ammoniac.  Sal-ammoniac as a crystal is obtained in various ways, principally from the ammoniacal liquor of gas works, also from the condensed products of the distillation of bones and other animal refuse in the preparation of animal charcoal, and which is of a highly alkaline nature.  This liquid is then treated with a slight excess of muriatic acid to neutralize the free alkali, and at the same time the carbonates and sulphides are decomposed with the evolution of carbonic acid and sulphureted hydrogen.  All animal matter, the meat, bones, etc., contain considerable carbon, while the nitrogen from which the ammonia is produced forms a smaller portion of the substance.  The object is then to get rid of the carbon and sulphur, leaving the nitrogen to combine, through chemical affinity, with a portion of the hydrogen of the water, the oxygen which is set free going to form the carbonic acid by combining with the carbon.  The liquor after being neutralized is evaporated to dryness, leaving a crystallized salt containing a portion of tarry matter.

Copyrights
Project Gutenberg
Scientific American Supplement No. 819, September 12, 1891 from Project Gutenberg. Public domain.