Scientific American Supplement No. 819, September 12, 1891 eBook

This eBook from the Gutenberg Project consists of approximately 130 pages of information about Scientific American Supplement No. 819, September 12, 1891.

Scientific American Supplement No. 819, September 12, 1891 eBook

This eBook from the Gutenberg Project consists of approximately 130 pages of information about Scientific American Supplement No. 819, September 12, 1891.

Reducing the Silver Sulphate to Fine Silver.—­The mother acid is pumped from C to the reservoir, B, for this purpose an iron pipe connecting the top of B with a recess in the bottom of C. The tank, B, is cast as a closed vessel, with a manhole in the top, which is ordinarily kept closed by an iron plate resting on a rubber packing.  The air is exhausted from B by a steam injector, and the acid rises from C and enters B without coming in contact with any valves.  The volume of fresh commercial acid necessary for another dissolving operation, say 800 pounds, more or less, for refining 800 pounds of bullion in A A, is lifted from some other receptacle into B in the same manner.  The mixture of the two acids in B now represents the volume of acid to be employed for dissolving and settling the next charge of 800 pounds of bullion in A A. In this reservoir, B, the cloud of lead sulphate mentioned above finds an opportunity for settling.

The crystals of silver sulphate are detached from C by an iron shovel and thrown into D. D is a lead lined tank about 4 ft. by 4 ft. and 3 ft. deep.  It is divided into two compartments by means of a horizontal, perforated false bottom made of wood.  From the lower compartment a lead pipe discharges into the lead lined reservoir, E. Warm distilled water is allowed to percolate the crystals until the usual ammonia test indicates that the copper sulphate has been sufficiently dissolved.  Then the outflow is closed, sheets of iron are thrown on and into the crystals, the apparatus is filled with hot distilled water, and steam is moderately admitted into the lower compartment.  Ferrous sulphate is formed, and in connection with the iron rapidly reduces the silver sulphate to the metallic state, the reduced silver retaining the heavy compact character of the crystals.  When the reaction is completed, as indicated by the chlorine test, the liquid is discharged into E, the iron sheets are removed and the silver is sweetened either in the same vessel, D, or in a special filtering vessel which rests on wheels and may be run directly to the hydraulic press.

The vat, E, is the great reservoir where all liquids holding silver sulphate in solution are collected; for instance, that from sweetening the gold and from washing the tools.  Sheets of iron here precipitate all silver and copper, and the resulting solution of ferrous sulphate is, with the usual precautions, discharged into the sewer.  Occasionally when copper and silver have accumulated in E in sufficient amount the mass is thrown into D, silver sulphate crystals are added and sheet copper is thrown in, instead of sheet iron.  There results a hot, neutral, concentrated solution of copper sulphate, which may be run at once into a crystallizing vat for the separation of commercial crystals of copper sulphate.  It will be readily understood, of course, that if there should be any advantage in manufacturing that commercial article, besides the amount prepared as described, which represents

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Scientific American Supplement No. 819, September 12, 1891 from Project Gutenberg. Public domain.