Scientific American Supplement No. 822, October 3, 1891 eBook

This eBook from the Gutenberg Project consists of approximately 149 pages of information about Scientific American Supplement No. 822, October 3, 1891.

Scientific American Supplement No. 822, October 3, 1891 eBook

This eBook from the Gutenberg Project consists of approximately 149 pages of information about Scientific American Supplement No. 822, October 3, 1891.

or as preferred by some:  H-O-H, is not in conformity with established facts.  Expressed as here shown, both hydrogen atoms are assigned equal values, when in fact only one of the atoms is united to oxygen in form of hydroxyl, while the second is loosely attached to the univalent hydroxyl group.  Viewed in this light, water then is decomposed according to the equation:  H_{2}O = H + (OH), never in this manner:  H_{2}O = 2H + O. Hence, water must be considered as a combination of one hydrogen atom with one molecule of hydroxyl, expressed by the formula H(OH), and it is this atom of hydrogen not united to oxygen which is eliminated in the generation of oxygen or substituted by metals and alkyl groups.  The hydrogen in the hydroxyl group cannot be substituted, excepting it be the entire group as such; this is proved by the action of the halogens, in their phosphorus compounds, upon water, when the halogen takes the place of the hydroxyl group, but never that of the hydrogen.

Now as to some logical deductions from the foregoing considerations.  Hydrogen is by many looked upon as a true metal.  This theory cannot be directly proved by the above, but it is certainly greatly strengthened thereby.  To compare.  Hydrogen is a powerful reducing agent; it is similarly affected by the halogens, the hydroxyl group, the acid radicals, oxygen and sulphur; hydrogen and members of the univalent alkali metals group are readily interchangeable; it forms superoxides analogous to the metals; its analogy to the alkali metals as exhibited in the following: 

    H H(OH) HCl HNO_{3} H_{2}SO_{4} H_{2}S H_{2}O_{2}
    K K(OH) KCl KNO_{3} Na_{2}SO_{4} Na_{2}S K_{2}O

But if we consider hydrogen as a gasiform metal, we naturally arrive at the conclusion that water is the hydroxide of this gasiform metal, that is hydrogen hydroxide, while gaseous hydrochloric and hydrosulphuric acids would be looked upon as respectively the chloride and the sulphide of the metal hydrogen.  This would then lead to curious conclusions concerning the hydroxyl group.  This group would, by this theory, become an oxygenated metal radical similar to the hypothetical bismuthyl and uranyl, and yet one in which the metallic character has disappeared as completely as in the ferrocyanic group.

An entirely new light is shed by this view upon the composition of hydrogen peroxide, which would be looked at as two free hydroxyl groups joined together thus:  (OH)—­(OH), analogous to our di-ethyl, diphenyl, dicyanogen, etc.  Considered as dihydroxyl, it would explain the instability of this compound.

The ethers proper would also be placed in a new light by this new conception of the constitution of the water molecule.  The hydrogen in the hydroxyl group, as is known, may be substituted by an alkyl group.  For instance, an alkyl may be substituted for the hydroxyl hydrogen in an alcohol molecule, when an ether results.  According to the new theory this ether will no longer be considered as two alkyl groups connected by an oxygen atom, but as a compound built up on the type of water by the union of an alkyl group and an alkoxyl group.  Thus ethylic ether would not be represented by

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Scientific American Supplement No. 822, October 3, 1891 from Project Gutenberg. Public domain.