Scientific American Supplement, No. 415, December 15, 1883 eBook

This eBook from the Gutenberg Project consists of approximately 118 pages of information about Scientific American Supplement, No. 415, December 15, 1883.

The Neueste Erfinderung describes an anti-corrosion paint for iron.  It states that if 10 per cent. of burnt magnesia, or even baryta, or strontia, is mixed (cold) with ordinary linseed-oil paint, and then enough mineral oil to envelop the alkaline earth, the free acid of the paint will be neutralized, while the iron will be protected by the permanent alkaline action of the paint.  Iron to be buried in damp earth may be painted with a mixture of 100 parts of resin (colophony), 25 parts of gutta-percha, and 50 parts of paraffin, to which 20 parts of magnesia and some mineral oil have been added.

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At a recent meeting of the Chemical Society, London, a paper was read entitled “Notes on the Condition in which Carbon exists in Steel,” by Sir F.A.  Abel, C.B., and W.H.  Deering.

Two series of experiments were made.  In the first series disks of steel 2.5 inches in diameter and 0.01 inch thick were employed.  They were all cut from the same strip of metal, but some were “cold-rolled,” some “annealed,” and some “hardened.”  The total carbon was found to be:  “cold-rolled,” 1.108 per cent.; hardened, 1.128 per cent.; and annealed, 0.924 and 0.860 per cent.  Some of the disks were submitted to the action of an oxidizing solution consisting of a cold saturated solution of potassium bichromate with 5 per cent. by volume of pure concentrated sulphuric acid.  In all cases a blackish magnetic residue was left undissolved.  These residues, calculated upon 100 parts of the disks employed, had the following compositions:  “Cold-rolled” carbon, 1.039 per cent.; iron, 5.871.  Annealed, C, 0.83 per cent.; Fe, 4.74 per cent.  Hardened, C, 0.178 per cent.; Fe, 0.70 per cent.  So that by treatment with chromic acid in the cold nearly the whole of the carbon remains undissolved with the cold-rolled and annealed disks, but only about one-sixth of the total carbon is left undissolved in the case of the hardened disk.  The authors then give a resume of previous work on the subject.  In the second part they have investigated the action of bichromate solutions of various strengths on thin sheet-steel, about 0.098 inch thick, which was cold-rolled and contained:  Carbon, 1.144 per cent.; silica, 0.166 per cent.; manganese, 0.104 per cent.  Four solutions were used.  The first contained about 10 per cent. of bichromate and 9 per cent. of H_{2}so_{4} by weight; the second was eight-tenths as strong, the third about half as strong, the fourth about one and a half times as strong.  In all cases the amount of solution employed was considerably in excess of the amount required to dissolve the steel used.  A residue was obtained as before.  With solution 1, the residue contained, C, 1.021; sol. 2, C, 0.969; sol. 3, C 1.049 the atomic ratio of iron to carbon was Fe 2.694:  C, 1; Fe, 2.65:  C, 1; Fe), 2.867 C, 1):  sol. 4.  C, 0.266 per 100 of steel.  The authors conclude that the carbon in cold rolled steel exists not simply diffused mechanically through the mass of steel but in the form of an iron carbide, Fe_{3}C, a definite product, capable of resisting the action of an oxidizing solution (if the latter is not too strong), which exerts a rapid solvent action upon the iron through which the carbide is distributed.

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Scientific American Supplement, No. 415, December 15, 1883 from Project Gutenberg. Public domain.
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